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An exception is Aroclor 1016, which also has 12 carbon atoms, but has 42% chlorine by mass.
Aroclor 1016 was prepared by the fractional distillation of Aroclor 1242, which excluded the higher boiling (i.e., more highly chlorinated) congeners.
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In PCBs, some of the hydrogen atoms in biphenyl are replaced by chlorine atoms.
There are 209 different chemical compounds in which one to ten chlorine atoms can replace hydrogen atoms.
Some PCBs share a structural similarity and toxic mode of action with dioxin.
As the degree of chlorination increases, melting point and lipophilicity increase, and vapour pressure and water solubility decrease.
They can generate extremely toxic dibenzodioxins and dibenzofurans through partial oxidation.
Another estimate put the total global production of PCBs on the order of 1.5 million tons.
The United States was the single largest producer with over 600,000 tons produced between 19.